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Preparation and Performance Evaluation of a Composite Crosslinking Agent

Received: 18 April 2018     Accepted: 3 May 2018     Published: 22 May 2018
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Abstract

A water-soluble phenolic resin composite crosslinking agent was synthesized by the combination of water-soluble phenolic resin and metal ions promote cross-linking agent. The water-soluble excellent multi-methylol phenolic resin was synthesized by two-step method, followed by addition of an appropriate amount of metal ions to improve their gelling properties. The two-step method could promote the reaction of phenol and formaldehyde, so the main product was multi-methylol phenolic resin. The introduction of metal ions promoted cross-linking agent to make excellent gelling properties. This new kind of crosslinking agent was odor less, low toxicity, and efficient. Based on this kind of water-soluble phenolic resin composite crosslinking agent, the partially hydrolysed polyacrylamide showed good gelling properties. The minimum amount of cross-linking agent was 0.1% with high gelling strength; its gelation temperature could be adjusted from 60°C-120°C and its gelling time could be controlled between 8h and 48h. The stability of gel system was more than 60 days. The composite crosslinking agent has great prospects in the field of oilfield water shutoff profile.

Published in American Journal of Applied Chemistry (Volume 6, Issue 3)
DOI 10.11648/j.ajac.20180603.11
Page(s) 71-77
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Crosslinking Agents, Phenolic Resin, Polyacrylamide, Gel Time, Metal Ions

References
[1] ZHAO G, DAI C, CHEN A, et al. Experimental study and application of gels formed by nonionic polyacrylamide and phenolic resin for in-depth profile control [J]. Journal of Petroleum Science and Engineering, 2015, 135: 552-560.
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[3] BAI B J, ZHOU J, YIN M F. A comprehensive review of polyacrylamide polymer gels for conformance control [J]. Petroleum Exploration and Development, 2015, 42(4): 481-487.
[4] El-KARSANI K S M, Al-MUNTASHERI G A, HUSSEIN I A. Polymer systems for water shutoff and profile modification: a review over the last decade [J]. SPE Journal, 2014, 19(1): 135-149.
[5] XU D J, ZHENG Y F, ZHAG S, et al. Application progress of weak gel systems in oilfield profile control technology [J]. Chemical Industry and Engineering Progress, 2015, 34(5): 1323-1331.
[6] Zhao X Y, LI X R, Ma G Y. A laboratory performance study on amphoteric hydrophobically associating polyacrylamide [J]. Applied Chemical Industry, 2018(2): 250-253.
[7] SHI J H, WEI X M. Synthesis and evaluation of polymer oil displacement agent crosslinked by phenolaldehyde resin prepolymer [J]. Advances in Fine Petrochemicals, 2003, 4(7): 45-48.
[8] Xi Z H, Dang G C, Wang L Y, et al. Performance research of copolymer fracturing fluid system [J]. Applied Chemical Industry, 2017, 10: 1934-1937.
[9] WANG J Y, Kong Y, Zhao C X, et al. Effect of polymer hydrolysis degree on the gel performance of organic chrome cross linker [J]. Chemical Engineer, 2015, 4: 75-76.
[10] TANG H Y, XIAO Q G, XU H B, et al. Progress of new chromium chemicals: organic chromium complexes [J]. Chemical Industry and Engineering Progress, 2013, 32 (9): 2205-2215.
[11] LI C N, LEI K, ZHU M D. Study on the synthesis and performance evaluation of aluminum citrate crosslinking agent [J]. Chemical Engineer, 2013(5): 14-16.
[12] JING Y, ZHANG S C, LV X. Preparation of particulated precrosslinked acrylamide tercopolymer/bentonite complex as diverting agent LJ-1 [J]. Oilfield Chemistry, 2005, 22(4): 354-357.
[13] LUO Y, LIU D N, HU Q P, et al. Microencapsulation of organic chromium crosslinker for polymer gelling fluid as water shutoff/profile modification agent [J]. Oilfield Chemistry, 2009, 26(4): 391-394.
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Cite This Article
  • APA Style

    Sun Lei, Zhang Guiqing, Xu Hongzhi, Hao Zhiwei, Xia Ye. (2018). Preparation and Performance Evaluation of a Composite Crosslinking Agent. American Journal of Applied Chemistry, 6(3), 71-77. https://doi.org/10.11648/j.ajac.20180603.11

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    ACS Style

    Sun Lei; Zhang Guiqing; Xu Hongzhi; Hao Zhiwei; Xia Ye. Preparation and Performance Evaluation of a Composite Crosslinking Agent. Am. J. Appl. Chem. 2018, 6(3), 71-77. doi: 10.11648/j.ajac.20180603.11

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    AMA Style

    Sun Lei, Zhang Guiqing, Xu Hongzhi, Hao Zhiwei, Xia Ye. Preparation and Performance Evaluation of a Composite Crosslinking Agent. Am J Appl Chem. 2018;6(3):71-77. doi: 10.11648/j.ajac.20180603.11

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  • @article{10.11648/j.ajac.20180603.11,
      author = {Sun Lei and Zhang Guiqing and Xu Hongzhi and Hao Zhiwei and Xia Ye},
      title = {Preparation and Performance Evaluation of a Composite Crosslinking Agent},
      journal = {American Journal of Applied Chemistry},
      volume = {6},
      number = {3},
      pages = {71-77},
      doi = {10.11648/j.ajac.20180603.11},
      url = {https://doi.org/10.11648/j.ajac.20180603.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180603.11},
      abstract = {A water-soluble phenolic resin composite crosslinking agent was synthesized by the combination of water-soluble phenolic resin and metal ions promote cross-linking agent. The water-soluble excellent multi-methylol phenolic resin was synthesized by two-step method, followed by addition of an appropriate amount of metal ions to improve their gelling properties. The two-step method could promote the reaction of phenol and formaldehyde, so the main product was multi-methylol phenolic resin. The introduction of metal ions promoted cross-linking agent to make excellent gelling properties. This new kind of crosslinking agent was odor less, low toxicity, and efficient. Based on this kind of water-soluble phenolic resin composite crosslinking agent, the partially hydrolysed polyacrylamide showed good gelling properties. The minimum amount of cross-linking agent was 0.1% with high gelling strength; its gelation temperature could be adjusted from 60°C-120°C and its gelling time could be controlled between 8h and 48h. The stability of gel system was more than 60 days. The composite crosslinking agent has great prospects in the field of oilfield water shutoff profile.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Preparation and Performance Evaluation of a Composite Crosslinking Agent
    AU  - Sun Lei
    AU  - Zhang Guiqing
    AU  - Xu Hongzhi
    AU  - Hao Zhiwei
    AU  - Xia Ye
    Y1  - 2018/05/22
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ajac.20180603.11
    DO  - 10.11648/j.ajac.20180603.11
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 71
    EP  - 77
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20180603.11
    AB  - A water-soluble phenolic resin composite crosslinking agent was synthesized by the combination of water-soluble phenolic resin and metal ions promote cross-linking agent. The water-soluble excellent multi-methylol phenolic resin was synthesized by two-step method, followed by addition of an appropriate amount of metal ions to improve their gelling properties. The two-step method could promote the reaction of phenol and formaldehyde, so the main product was multi-methylol phenolic resin. The introduction of metal ions promoted cross-linking agent to make excellent gelling properties. This new kind of crosslinking agent was odor less, low toxicity, and efficient. Based on this kind of water-soluble phenolic resin composite crosslinking agent, the partially hydrolysed polyacrylamide showed good gelling properties. The minimum amount of cross-linking agent was 0.1% with high gelling strength; its gelation temperature could be adjusted from 60°C-120°C and its gelling time could be controlled between 8h and 48h. The stability of gel system was more than 60 days. The composite crosslinking agent has great prospects in the field of oilfield water shutoff profile.
    VL  - 6
    IS  - 3
    ER  - 

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Author Information
  • Engineering Technology Research Company Limited, China National Petroleum Corporation, Tianjin, China

  • Engineering Technology Research Company Limited, China National Petroleum Corporation, Tianjin, China

  • Engineering Technology Research Company Limited, China National Petroleum Corporation, Tianjin, China

  • Engineering Technology Research Company Limited, China National Petroleum Corporation, Tianjin, China

  • Engineering Technology Research Company Limited, China National Petroleum Corporation, Tianjin, China

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